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Probing and Mapping Electrode Surfaces in Solid Oxide Fuel Cells
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Published on: September 20, 2012

A new anode for solid oxide fuel cells with enhanced OCV under methane operation.

Juan C Ruiz-Morales1, Jesús Canales-Vázquez, Cristian Savaniu

  • 1School of Chemistry, University of St Andrews, St Andrews, Fife, UK KY16 9ST.

Physical Chemistry Chemical Physics : PCCP
|April 7, 2007
PubMed
Summary

A novel oxygen-excess perovskite anode material for solid oxide fuel cells (SOFCs) demonstrates superior performance in hydrogen and methane fuels. This new SOFC anode material exhibits excellent stability and power density, outperforming current standards.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Conversion

Background:

  • Solid Oxide Fuel Cells (SOFCs) are advanced energy conversion devices.
  • Developing efficient and stable anode materials is crucial for SOFC performance.
  • Current state-of-the-art anodes, like Ni-YSZ cermets, have limitations, especially with hydrocarbon fuels.

Purpose of the Study:

  • To synthesize and characterize a new SOFC anode material based on oxygen-excess perovskite related phases.
  • To evaluate its electrochemical performance under hydrogen and methane fuel conditions.
  • To assess the material's stability and performance under various operating conditions and configurations.

Main Methods:

  • Synthesis of oxygen-excess perovskite related phases for SOFC anodes.
  • Electrochemical performance testing under humidified H(2) and CH(4) at 950°C.
  • Anode configuration studies (one-layer and four-layer).
  • Long-term stability testing under alternating reducing/oxidizing conditions and temperature cycling.

Main Results:

  • The new material shows better electrochemical performance than alternative new anodes and comparable performance to Ni-YSZ cermets under H(2).
  • Enhanced performance under methane operation with high open circuit voltages (1.2-1.4 V at 950°C) without excess steam.
  • Optimized electrode polarization resistances of 0.12 ohm cm(2) (H(2)) and 0.36 ohm cm(2) (CH(4)) at 950°C.
  • Power densities of 0.5 W cm(-2) (H(2)) and 0.35 W cm(-2) (CH(4)) achieved.
  • Very low anodic overpotential (100 mV at 1 A cm(-2)) under humidified H(2) at 950°C.
  • Stable electrode performance and open circuit voltages demonstrated over two days of testing.

Conclusions:

  • Substituted strontium titanates are highly promising anode materials for SOFCs.
  • The developed material offers excellent performance and stability, particularly for methane utilization.
  • This research contributes to the advancement of SOFC technology for efficient energy conversion.