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Updated: Jul 15, 2026

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
Development of a general and efficient iron-catalyzed epoxidation with hydrogen peroxide as oxidant
Bianca Bitterlich1, Gopinathan Anilkumar, Feyissa Gadissa Gelalcha
1Leibniz-Institut für Katalyse, Albert-Einstein-Str. 29a, D-18059 Rostock, Germany.
Abstract:
The development of inexpensive and practical iron catalysts for the environmentally benign epoxidation of olefins with hydrogen peroxide as terminal oxidant is described. By systematic variation of ligands, metal sources, and reaction conditions, it was discovered that FeCl3 x 6 H2O in combination with pyridine-2,6-dicarboxylic acid and different amines shows high reactivity and excellent selectivity towards the epoxidation of aromatic olefins and moderate reactivity towards that of aliphatic olefins.
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