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Updated: Jul 15, 2026

Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
Published on: August 25, 2016
Dynamical aspects of the adsorption hysteresis phenomenon
Rustem Valiullin1, Sergej Naumov, Petrik Galvosas
1Fakultät für Physik und Geowissenschaften, Universität Leipzig, D-04103 Leipzig, Germany. valiullin@uni-leipzig.de
Abstract:
Equilibrium and nonequilibrium transport properties of adsorbates in mesoporous Vycor porous glass have been experimentally studied using nuclear magnetic resonance techniques. With the known geometrical characteristics of porous glass and with measured self-diffusivities, transient sorption curves have been quantitatively compared to those predicted within a Fick's law model. This model correctly describes data outside a hysteresis region. In contrast, in the hysteresis region, a two-step mechanism of density relaxation is required to explain the behavior. These two mechanisms are identified as diffusion at early stages and activated density redistribution at later stages of adsorption. The latter mechanism, being intrinsically slow in nature, is anticipated to prevent the system from reaching equilibrium.
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