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Adapting Taylor Dispersion to Measure the Dispersion Coefficient of Electrolyte Solutions via an Accessible Microfluidic Setup
Published on: October 7, 2025
A new method for laboratory estimation of the transverse dispersion coefficient
Marco Massabò1, Federico Catania, Ombretta Paladino
1DIST-Dipartimento di Informatica, Sistemistica e Telematica, University of Genoa, Via Cadorna 7, 17100 Savona, Italy. m.marco@cima.unige.it
Abstract:
We introduce a method for identifying the transverse dispersion coefficient in laboratory experiments based on the analytical solution of a pulse injection of a nonreactive solute in a soil column (cylindrical geometry) packed with a homogeneous porous medium. This method takes into account the effect of boundary conditions such as no flux on the column perimeter, and it does not need a priori knowledge of the longitudinal dispersion coefficient. Numerical applications of the method show that it is stable and robust and that the results are reasonably in accordance with those found using the classical maximum likelihood method.

