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Metal-oxide-based nucleation process under confined conditions: two mixed-valence V6-type aggregates closing the W48

Achim Müller1, Michael T Pope, Ana Maria Todea

  • 1Fakultät für Chemie der Universität, Postfach 100131, 33501 Bielefeld, Germany. a.mueller@uni-bielefeld.de

Angewandte Chemie (International Ed. in English)
|May 10, 2007
PubMed
Abstract

No abstract available in PubMed .

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Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...

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