After 20 years, theoretical evidence that "AuF(7)" is actually AuF(5) x F(2)
Daniel Himmel1, Sebastian Riedel
1Institut für Anorganische und Analytische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21, D-79104 Freiburg i. Br., Germany.
Abstract:
Quantum-chemical calculations at the DFT (BP86, PBE, TPSS, B3LYP, PBE0), MP2, CCSD, and CCSD(T) levels have been carried out to characterize the putative AuF(7) reported in 1986 by Timakov et al. Our calculations indicate clearly that the species claimed to be AuF(7) had not been synthesized. Instead, a new gold fluoride complex AuF(7) x F2 was prepared. This complex is 205 kJ mol(-1) more stable than the proposed AuF(7) species, and the elimination of F(2) is calculated to be endothermic. This is consistent with the reported stability of the product. A reported experimental vibrational frequency at 734 cm(-1) was verified computationally to be the F-F stretching mode of the end-on coordinated F2 molecule. This result is in line with the recently published trends in the highest attainable oxidation states of the 5d transition metals where Au(V) remains the highest oxidation state of gold.
Related Concept Videos
The Aufbau Principle and Hund's Rule
Valence Bond Theory and Hybridized Orbitals
A σ bond (single bond in a Lewis structure) is a covalent bond in which the electron density is...
Molecular Orbital Theory II
Hybridization of Atomic Orbitals II
Five-Membered Heterocyclic Aromatic Compounds: Overview
Molecular Orbital Theory I


