A tightly coupled bis(zinc(II) phthalocyanine)-perylenediimide ensemble to yield long-lived radical ion pair states
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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Angel J Jiménez1, Fabian Spänig, M Salomé Rodríguez-Morgade
1Departamento de Química OrgAnica, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain.
Abstract:
A conjugated donor-acceptor array composed of two phthalocyanines connected to the bay region of a perylenediimide is assembled by using palladium chemistry. Excitation of the phthalocyanine produces a nanosecond lived charge-separated state.
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