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Updated: Jul 14, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
Published on: June 14, 2024
Layer-by-layer growth of oriented metal organic polymers on a functionalized organic surface
O Shekhah1, H Wang, T Strunskus
1Lehrstuhl für Physikalische Chemie 1 and Organometallics and Materials Chemistry, Ruhr-Universität Bochum, 44780 Bochum, Germany.
Abstract:
A metal-organic coordination polymer based on benzenetricarboxylic acid ligands and Zn(II) ions was grown on a COOH-terminated organic surface in a stepwise fashion. The deposited films were characterized using a number of surface analysis techniques, including X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. IR measurements show that the metal-organic coordination polymer grows in a layer-by-layer fashion and can be reversibly loaded with NH3. The deposition is very selective and occurs only on COOH-terminated regions of an organic surface, as demonstrated by AFM measurements.
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