trans-[1,3-Bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido(triphenylphosphine-kappaP)palladium(II)
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![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Resul Sevinçek1, Hayati Türkmen, Muhittin Aygün
1Department of Physics, Dokuz Eylül University, Buca, Izmir, Turkey.
Abstract:
The title complex, [PdCl(2)(C(21)H(26)N(2))(C(18)H(15)P)], shows slightly distorted square-planar coordination around the Pd(II) metal centre. The Pd-C bond distance between the N-heterocyclic ligand and the metal atom is 2.028 (5) A. The dihedral angle between the two trimethylphenyl ring planes is 36.9 (2) degrees.
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