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Phosphorus removal from soy protein wastewater using novel crystallisation technology.
1DuPont Company, 1007 Market Street, Wilmington, DE 19898, USA. kenneth.n.wood@usa.dupont.com
Summary
This study presents a novel crystallization technology for treating soy protein isolate wastewater, effectively reducing phosphorus to 2 mg L(-1) total P. The method uses lime precipitation in a HARDTAC crystallizer, producing fast-settling particles with minimal sludge and lime use.
Area of Science:
- Environmental Engineering
- Chemical Engineering
- Water Treatment Technologies
Background:
- Soy protein isolate manufacturing generates wastewater with high phosphorus content.
- Stringent regulations necessitate phosphorus reduction in industrial wastewater discharge.
- Existing treatment methods may increase soluble salts or be inefficient.
Purpose of the Study:
- To identify and implement a wastewater treatment method to reduce total phosphorus (P) to 2 mg L(-1).
- To achieve phosphorus reduction without increasing soluble salt concentrations.
- To comply with environmental discharge and receiving-water requirements.
Main Methods:
- Evaluation of a novel crystallization technology, the high-aspect ratio, draft tube crystalliser (HARDTAC).
- Pilot studies and full-scale implementation of lime precipitation at pH 10.0-10.2.
- Characterization of particle settling, filterability, and crystal size distribution.
Main Results:
- Achieved average total phosphorus reduction to 2 mg L(-1).
- Produced rapid settling particles (3.6 cm min(-1)) and filterable cake (65% dry solids).
- Minimal carbonate removal resulted in low sludge generation (0.6-0.8 g/L) and lime consumption (0.40-0.75 g/L).
Conclusions:
- The HARDTAC crystallization technology effectively treats soy protein isolate wastewater for phosphorus removal.
- The method meets stringent discharge limits without increasing soluble salts.
- The system offers an efficient and cost-effective solution for industrial phosphorus management.
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