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Updated: Jul 14, 2026

Characteristics of Precipitation-formed Polyethylene Glycol Microgels Are Controlled by Molecular Weight of Reactants
Published on: December 23, 2013
Influence of poly(ethylene glycol) molecular mass on separation and ordering in solutions of CiEj nonionic
S Makulska1, E Chudy, K Urbaniak
1WMP-SNS, Cardinal Stefan Wyszynski University, Dewajtis 5, 01-815 Warsaw, Poland.
Abstract:
We study ternary mixtures of nonionic surfactants C(i)E(j) (i = 12; j = 5, 6, 8) and poly(ethylene glycol) (PEG) in water. For sufficiently large molecular mass of PEG (M >M(sep) approximately 600), we observe a lowering of phase separation temperature with an increase in polymer concentration. The value of M(sep) is consistent with the analysis based on depletion interactions between micelles induced by polymer chains. We also demonstrate that there is another critical molecular mass of PEG (M = M* approximately 2000) necessary to induce ordering in the surfactant-rich phase. This critical molecular mass follows from two requirements: (a) PEG has to reduce the separation temperature below a temperature of hexagonal-isotropic phase transition in a binary surfactant-water mixture and (b) the PEG radius of gyration has to be larger than the size of the water channels in the hexagonal phase.
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