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Solubility03:00

Solubility

Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules, atoms, and/or ions)...
Solubility Equilibria03:07

Solubility Equilibria

Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation.
The...
Solubility Equilibria: Overview01:09

Solubility Equilibria: Overview

When a substance such as sodium chloride is added to water, it dissolves, forming an aqueous solution. The extent of dissolution is called solubility. The process of dissolution can exist in equilibrium, just like other chemical processes. Solubility equilibria are also called precipitation equilibria because the process of solubility can be reversible. The reverse of the solubility process is called precipitation.
Solubility is important in biological and environmental processes. A notable...
Supercritical Fluid Chromatography01:18

Supercritical Fluid Chromatography

Supercritical fluid chromatography (SFC) provides a beneficial substitute for gas chromatography (GC) and liquid chromatography (LC) for certain samples because it merges the top attributes of both techniques. SFC allows the separation and analysis of compounds that GC or LC does not easily manage. These compounds are traditionally nonvolatile or thermally unstable, making GC unsuitable and lacking functional groups required for HPLC analysis.
SFC utilizes a supercritical fluid mobile phase,...
Solution Formation02:16

Solution Formation

There is no one solvent that can dissolve every type of solute. Some substances that readily dissolve in a certain solvent might be insoluble in a different solvent. A simple way to predict which substances dissolve in which solvent is the phrase "like dissolves like". This means that polar substances, such as salt and sugar, dissolve in a polar substance like water. In contrast, non-polar substances are more soluble in non-polar solvents such as carbon tetrachloride.
This selective solubility...
Liquid–Solid Solutions01:29

Liquid–Solid Solutions

The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...

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Related Experiment Video

Updated: Jul 14, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
16:24

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

Published on: August 2, 2012

Probing solute clustering in supercritical solutions using solvatochromic parameters.

Andrew P Abbott1, Eric G Hope, Donna J Palmer

  • 1Chemistry Department, University of Leicester, Leicester, LE1 7RH, U.K. andrew.abbott@le.ac.uk

The Journal of Physical Chemistry. B
|June 23, 2007
PubMed
Summary

Supercritical fluid polarity was measured using Kamlet and Taft parameters. Solute properties like polarizability and hydrogen-bond-donating ability significantly changed with pressure, impacting solution polarity.

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Last Updated: Jul 14, 2026

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Area of Science:

  • Physical Chemistry
  • Supercritical Fluids
  • Solution Chemistry

Background:

  • Kamlet and Taft polarity parameters are crucial for understanding solute-solvent interactions.
  • Supercritical fluids exhibit unique properties that can be tuned with pressure and temperature.
  • Investigating polarity in supercritical solutions provides insights into molecular behavior under extreme conditions.

Purpose of the Study:

  • To present Kamlet and Taft polarity parameters for supercritical solutions.
  • To analyze the influence of pressure and solute concentration on polarity.
  • To elucidate the relationship between polarizability, hydrogen-bond-donating ability, and solution polarity.

Main Methods:

  • Measurement of Kamlet and Taft polarity parameters in supercritical solutions.
  • Systematic variation of solute type, concentration, and pressure.
  • Analysis of solute-solute and solute-indicator clustering effects.

Main Results:

  • Polarity parameters significantly varied with pressure, affecting polarizability and hydrogen-bond-donating ability.
  • Naphthalene and salicylic acid decreased polarity at lower pressures, while toluic acid increased it.
  • A direct correlation was observed between changes in hydrogen-bond-donating ability and polarizability across all conditions.

Conclusions:

  • Solute-solute and solute-indicator clustering influence polarity in supercritical solutions.
  • Changes in solvent solvation are linked to observed correlations between hydrogen-bond-donating ability and polarizability.
  • Pressure is a key factor in modulating the polarity and solvation characteristics of supercritical fluid solutions.