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Updated: Jul 14, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Sol-gel materials doped with 3-(3-(4-(dimethylamino)phenyl)propenoyl)-2H-chromen-2-one: spectroscopic and structural
1University of Sofia St. Kliment Ohridski, Faculty of Chemistry, Department of Analytical Chemistry, 1 James Bauchier Boulevard, 1164 Sofia, Bulgaria. BKoleva@chem.uni-sofia.bg
Abstract:
Conventional and linear-polarized IR-spectroscopic tools based on reducing-difference procedures for non-polarized and polarized IR-spectra interpretation as well as orientation technique of solids (colloidal suspension in nematic liquid crystal) and UV/vis spectroscopy are applied for investigation of new sol-gel materials with potential optical application of doped organic dye 3-(3-(4-(dimethylamino)phenyl)propenoyl)-2H-chromen-2-one (K2) and Sm3+ ions. The results show that during aging of the monoliths Sm3+ forms an unstable complex with K2, [Sm(K2)(2)(H2O2](NO3)(3), which transforms to [Sm(H2O)(6)](3+) one, typical for gel-Sm3+ system. Quantum chemical ab initio and DFT calculations are reported with a view to support experimental IR-characteristic bands of the system studied.
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