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Lower-rim substituted calixarenes and their applications
1Department of Chemistry, School of Sciences, Gujarat University, Navrangpura, Ahmedabad 380009, Gujarat, India. blossoms_joy2003@yahoo.co.in
Bioinorganic Chemistry and Applications
|July 6, 2007
Summary
This review details calixarenes, focusing on lower-rim modified structures and their supramolecular chemistry applications. It critically evaluates synthesis methods for these versatile compounds.
Area of Science:
- Supramolecular Chemistry
- Organic Chemistry
Background:
- Calixarenes were initially discovered as by-products of phenol formaldehyde bakelite production.
- Significant advancements have occurred since their discovery, expanding their role in chemistry.
Purpose of the Study:
- To provide a detailed review of calixarenes.
- To concentrate on lower-rim modified calixarenes and their applications.
- To critically evaluate synthesis procedures for lower-rim substituted calixarenes.
Main Methods:
- Literature review focusing on lower-rim modified calixarenes.
- Critical evaluation of synthesis methodologies.
Main Results:
- Calixarenes have evolved significantly, becoming key players in supramolecular chemistry.
- Lower-rim modified calixarenes exhibit diverse potential applications.
- Synthesis routes for these modified calixarenes have been critically assessed.
Conclusions:
- Calixarenes are versatile molecules with a growing impact on supramolecular chemistry.
- Lower-rim modification offers a pathway to tailored calixarene properties and applications.
- Understanding and optimizing synthesis is crucial for advancing calixarene chemistry.
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