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Updated: Jul 13, 2026

Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
Space-time contours to treat intense field-dressed molecular states. II. Applications
Biplab Sarkar1, Satrajit Adhikari, Michael Baer
1Department of Chemistry, Indian Institute of Technology, Guwahati, North Guwahati, Guwahati 781039, India.
Abstract:
This second article in the two back-to-back articles presents a numerical application to support and strengthen two theoretical findings extensively discussed in the previous article (article I). In I, we found that introducing the space-time contours enables to distinguish between N, the number of nuclear Schrodinger equations to be solved, and L, the number of field-free states that become populated by the external field (in the ordinary, perturbative approaches this distinction is not apparent). In the numerical study we show, employing the electronic transition probability matrix P(s,t) [which closely is related to the transformation matrix omega(s,t)--see Eqs. (21) and (25) in I], that the N=L case is rare and in most cases we have N
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