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A photochemical route to discrete, ternary metal chalcogenide clusters
Mark Williams1, Rawda M Okasha, Justin Nairn
1Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA.
Abstract:
Ternary clusters Cu(9)In(10)S(9)(SEt)(21)(PPh(3))(3) and Cu(11)In(6)S(7)(S(t)Bu)(15) were isolated from the UV-photolysis products of precursors (PPh(3))(2)CuIn(SEt)(4) and (PPh(3))(2)CuIn(S(t)Bu)(4), respectively, and structurally characterized.
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