Infrared photodissociation spectroscopy of Na(NH3)n clusters: probing the solvent coordination
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Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
Published on: March 22, 2019
Tom E Salter1, Victor Mikhailov, Andrew M Ellis
1Department of Chemistry, University of Leicester, University Road, Leicester, LE1 7RH, United Kingdom.
Abstract:
The first mass-selective vibrational spectra have been recorded for Na(NH3)n clusters. Infrared spectra have been obtained for n = 3-8 in the N-H stretching region. The spectroscopic work has been supported by ab initio calculations carried out at both the DFT(B3LYP) and MP2 levels, using a 6-311++G(d,p) basis set. The calculations reveal that the lowest energy isomer for n
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