Related Experiment Video
Updated: Jul 13, 2026

Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion
Published on: May 9, 2025
11B MAS NMR spectroscopic study of structural relaxation, aging, and memory effect at the atomic scale in a
Sezen Soyer Uzun1, Sabyasachi Sen
1Department of Chemical Engineering and Materials Science, University of California at Davis, One Shields Avenue, Davis, California 95616, USA.
Abstract:
Relaxation kinetics of boron coordination environments in a borosilicate glass in response to temperature jumps has been monitored using (11)B magic-angle spinning (MAS) NMR spectroscopy. The relaxation time scale of the BO4/BO3 ratio is found to be closely comparable with those of the bulk properties, namely, refractive index and viscosity, showing a close connection with one another. Samples partially equilibrated at a low temperature, when subjected to a positive temperature jump, display an initial rapid decrease followed by an increase in the BO4/BO3 ratio. This reversal in the trend of the variation of the BO4/BO3 ratio has been interpreted to be the signature of a memory effect, and the implications are discussed within the framework of the potential energy landscape model of glassy dynamics.
More Related Videos
08:55Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
09:25NMR 15N Relaxation Experiments for the Investigation of Picosecond to Nanoseconds Structural Dynamics of Proteins
Published on: November 1, 2024
Related Concept Videos
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
According to Hooke's law, the vibrational frequency is directly proportional to the...
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations
¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR