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Updated: Jul 13, 2026

Ligand-Mediated Nucleation and Growth of Palladium Metal Nanoparticles
Published on: June 25, 2018
Ergodic model for the expansion of spherical nanoplasmas
1Dipartimento di Energetica, Politecnico di Torino, 10129 Torino, Italy. fabio.peano@ist.utl.pt
Abstract:
Recently, the collisionless expansion of spherical nanoplasmas has been analyzed with a new ergodic model, clarifying the transition from hydrodynamiclike to Coulomb-explosion regimes, and providing accurate laws for the relevant features of the phenomenon. A complete derivation of the model is presented here. The important issue of the self-consistent initial conditions is addressed by analyzing the initial charging transient due to the electron expansion, in the approximation of immobile ions. A comparison among different kinetic models for the expansion is presented, showing that the ergodic model provides a simplified description, which retains the essential information on the electron distribution, in particular, the energy spectrum. Results are presented for a wide range of initial conditions (determined from a single dimensionless parameter), in excellent agreement with calculations from the exact Vlasov-Poisson theory, thus providing a complete and detailed characterization of all the stages of the expansion.
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