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Updated: Jul 13, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
SANS study of polymer-linked droplets
S Maccarrone1, H Frielinghaus, J Allgaier
1Institut für Festkörperforschung, Forschungszentrum Jülich, 52428 Jülich, Germany. maccarrone@lcvn.univ-montp2.fr
Abstract:
We report experimental results obtained from SANS on microemulsion droplets connected by a telechelic polymer. Thanks to its ability to anchor droplets through its short stickers, the addition of this polymer leads to the formation of transient aggregates. Measurements were performed on samples at low surfactant content in such a way that the droplets appear to be isolated with a separation distance longer than the end-to-end distance of the polymer. The locally spherical structure of the micelles is unchanged in size upon polymer addition whereas the large rise in scattered intensity at low Q is due to the induced effective attractive interaction between droplets. The fitting model that we propose allows a quantitative description of the bridging effect.
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