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Published on: March 7, 2019
Boron removal from aqueous solutions by ion-exchange resin: column sorption-elution studies
1Department of Chemical Engineering, Engineering and Architecture Faculty, Eskişehir Osmangazi University, 26480 Meşelik-Eskişehir, Turkey. ennilb@ogu.edu.tr
Abstract:
A column sorption-elution study was carried out by using a strong base anion-exchange resin (Dowex 2 x 8) for the removal of boron from aqueous solutions. The breakthrough curve was obtained as a function of feed flow rate and the total and breakthrough capacity values of the resin were calculated. The boron on the resin was quantitatively eluted with 0.5M HCl solution at different flow rates. Three consecutive sorption-elution-washing-regeneration-washing cycles were applied to the resin in order to investigate the reusability of the ion-exchange resin. Total capacity values remained almost the same after three sorption-elution-regeneration cycles. The Thomas and the Yoon-Nelson models were applied to experimental data to predict the breakthrough curves and to determine the characteristic column parameters required for process design. The results proved that the models would describe the breakthrough curves well.
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