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Published on: July 10, 2015
Heavy metals mobility in full-scale bioreactor landfill: initial stage.
Xian Qu1, Pin-Jing He, Li-Ming Shao
1State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai, 200092, People's Republic of China.
Heavy metals (HMs) release from bioreactor landfills decreased significantly after the methanogenic stage was established. Early methanogenesis reduced overall HM pollution, despite initial high releases.
Area of Science:
- Environmental Science
- Geochemistry
- Waste Management
Background:
- Landfills are significant sources of heavy metal (HM) pollution.
- Bioreactor landfills offer potential for enhanced waste decomposition and contaminant control.
- Understanding HM behavior during early landfill operation is crucial for environmental protection.
Purpose of the Study:
- To monitor the release of selected heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) during the initial 20 months of a full-scale bioreactor landfill.
- To investigate the factors influencing heavy metal mobility, particularly the role of humic substances.
- To evaluate the impact of leachate recirculation on heavy metal release dynamics.
Main Methods:
- Monitoring of heavy metal concentrations in landfill leachate.
- Analysis of leachate parameters including TOC and pH.
- Fourier-transform infrared (FT-IR) spectroscopy.
- Chemical speciation modeling using Visual MINTEQ.
Main Results:
- High initial heavy metal release was observed, correlating with high organic matter and low pH.
- Establishment of the methanogenic stage by month five led to heavy metal release below Chinese National Standards.
- Total heavy metal release was less than 1% of deposited material, with most being inorganic.
- Humic substances significantly influenced the mobility of organic heavy metal fractions.
Conclusions:
- The early establishment of the methanogenic stage is key to controlling heavy metal pollution in bioreactor landfills.
- Leachate recirculation can initially increase heavy metal release rates but may reduce total release through accelerated methanogenesis.
- Humic substances play a critical role in the fate and transport of heavy metals within the landfill environment.
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