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Updated: Jul 12, 2026

Reactive Vapor Deposition of Conjugated Polymer Films on Arbitrary Substrates
Published on: January 17, 2018
Self-condensing vinyl polymerization: an approach to dendritic materials
Abstract:
Self-condensing vinyl polymerization was used to produce dendritic polymers with both highly branched structures and numerous reactive groups. A vinyl monomer will undergo self-polymerization if it contains a pendant group that can be transformed into an initiating moiety by the action of an external stimulus. The self-polymerization combines features of a classical vinyl polymerization process with those of a polycondensation because growth is accomplished by the coupling of reactive oligomers. Highly branched, irregular dendritic structures with a multiplicity of reactive functionalities are obtained by polymerization of 3-(1-chloroethyl)-ethenylbenzene.
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