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Related Concept Videos

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Network Covalent Solids02:18

Network Covalent Solids

Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Imperfections in Crystal Structure: Stoichiometric Point Defects01:26

Imperfections in Crystal Structure: Stoichiometric Point Defects

Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...
Electrochemistry: Overview01:04

Electrochemistry: Overview

Electrochemistry is the branch of chemistry that studies the relationship between electrical quantities and chemical reactions, particularly oxidation and reduction. Oxidation is the loss of electrons from a substance, whereas reduction refers to the gain of electrons. A substance with a strong electron affinity is called an oxidizing agent (oxidant), and a reducing agent (reductant) is a species that donates electrons. Oxidation and reduction processes are pivotal to electrochemical reactions,...
Bonding in Metals02:32

Bonding in Metals

Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
What is Physical Chemistry?01:23

What is Physical Chemistry?

Physical chemistry is a branch of chemistry that studies the principles from physics underlying chemical reactions. It provides deep insights into the behaviors of molecules, the forces they experience, and their interactions and chemical reactions.The term "physical chemistry" was introduced by Mikhail Lomonosov in 1752. Since then, it has seen significant contributions from notable scientists such as Josiah Willard Gibbs, Wilhelm Ostwald, Jacobus Henricus van't Hoff, and Linus Pauling.Key...

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Related Experiment Video

Updated: Jul 12, 2026

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
11:33

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics

Published on: January 19, 2018

Solid-state chemistry: a a rediscovered chemical frontier.

F J Disalvo

    Science (New York, N.Y.)
    |February 9, 1990
    PubMed
    Summary

    Predicting new materials is challenging due to complex chemical bonding in solids. Researchers are exploring novel solid-state chemistry and synthesis methods to overcome these hurdles.

    Area of Science:

    • Solid-state chemistry
    • Materials science
    • Chemical physics

    Background:

    • Understanding chemical bonding in solids remains a significant challenge.
    • The vast diversity of elemental properties complicates materials prediction.
    • Synthesizing novel materials often relies on empirical methods rather than predictive science.

    Purpose of the Study:

    • To explore long-standing challenges in solid-state chemistry.
    • To highlight the difficulties in predicting material composition, structure, and properties.
    • To present ongoing research efforts at Cornell University focused on synthesizing new solid materials.

    Main Methods:

    • Review of fundamental principles governing chemical bonding in solids.
    • Analysis of factors contributing to the complexity of materials discovery.

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    Published on: June 9, 2023

    From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
    06:44

    From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

    Published on: March 24, 2018

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    Last Updated: Jul 12, 2026

    All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
    11:33

    All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics

    Published on: January 19, 2018

    Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
    06:53

    Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

    Published on: June 9, 2023

    From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
    06:44

    From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

    Published on: March 24, 2018

  • Experimental synthesis and characterization of novel solid compounds.
  • Main Results:

    • Identification of key challenges in predicting solid-state properties.
    • Demonstration of nature's versatility in forming diverse compounds and structures.
    • Progress in developing new synthetic approaches for novel materials.

    Conclusions:

    • Solid-state chemistry requires further advancements for accurate predictive capabilities.
    • The synthesis of new materials continues to be an area of active research and discovery.
    • Cornell's research contributes to expanding the landscape of known solid materials and their properties.