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Polyelectrolytes: potential chloroform precursors.

K L Kaiser, J Lawrence

    Science (New York, N.Y.)
    |June 10, 1977
    PubMed
    Summary
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    Widely used polyelectrolyte coagulants can form chloroform, a disinfection byproduct, in drinking water. This reaction is enhanced by heat and UV light, necessitating further research into polyelectrolyte safety.

    Area of Science:

    • Environmental Chemistry
    • Water Treatment
    • Organic Chemistry

    Background:

    • Chloroform in potable water is typically attributed to the chlorination of natural organic matter.
    • Polyelectrolytes are extensively used as coagulants and coagulant aids in water treatment processes.
    • The potential for polyelectrolytes to contribute to disinfection byproduct formation has not been well-established.

    Purpose of the Study:

    • To investigate the formation of chloroform from commercial polyelectrolyte formulations.
    • To determine the influence of thermal conditions and ultraviolet irradiation on this reaction.
    • To assess the implications of polyelectrolyte use on drinking water quality.

    Main Methods:

    • Testing of ten commercial polyelectrolyte formulations.

    Related Experiment Videos

  • Reaction of polyelectrolytes with chlorine under thermal conditions.
  • Evaluation of the effect of ultraviolet irradiation on chloroform formation.
  • Main Results:

    • Chloroform was formed from most tested polyelectrolyte formulations when reacted with chlorine.
    • Concentrations of chloroform reached several micrograms per liter.
    • The reaction was significantly activated by ultraviolet irradiation.

    Conclusions:

    • Polyelectrolyte coagulants and aids can be a source of chloroform in treated water.
    • Further research is needed due to the unknown chemical composition of polyelectrolytes and their impurities.
    • A comprehensive assessment of polyelectrolyte benefits versus potential harm is required.