The spontaneity of a process depends upon the temperature of the system. Phase transitions, for example, will proceed spontaneously in one direction or the other depending upon the temperature of the substance in question. Likewise, some chemical reactions can also exhibit temperature-dependent spontaneities. To illustrate this concept, the equation relating free energy change to the enthalpy and entropy changes for the process is considered:

The total work done on an object acted upon by multiple forces can be computed using two methods that give the same result. In one method, the work done by each force is first calculated. Then, those values are summed algebraically to calculate the total work done by all the forces. In the second method, the net force is first calculated by a vector sum of all the forces. Then, the work done by this force is obtained.
Since forces perpendicular to the displacement do no work, they do not...

One of the challenges of using the second law of thermodynamics to determine if a process is spontaneous is that it requires measurements of the entropy change for the system and the entropy change for the surroundings. An alternative approach involving a new thermodynamic property defined in terms of system properties only was introduced in the late nineteenth century by American mathematician Josiah Willard Gibbs. This new property is called the Gibbs free energy (G) (or simply the free...

Gravitation is one of the four fundamental forces in nature. The force between objects on Earth and Earth itself is called gravity.
Like other forces, gravity does work on an object if it displaces it toward the Earth's center. In this case, the work done by gravity is said to be positive. If an external force acts on the object against the pull of gravity and manages to lift it away from the Earth's center, work is done against gravity. In this case, the net work done is said to be negative.

The First Law of Thermodynamics states that energy cannot be created or destroyed, only transformed. This can be demonstrated within a classic food web where light energy from the sun is harnessed as radiant energy by plants, converted into chemical energy, and stored as complex carbohydrates. The vegetation is then consumed by animals and during the digestion process, the sugars release energy as heat. The sugars also produce chemical energy that either gets used up doing work, stored in...

A change in the internal energy of a system depends on the the net heat transfer into the system and the net work done by the system. The first law of thermodynamics, which is a generalized form of energy conservation, relates these three quantities mathematically. It states that the change in the internal energy equals the difference between the heat transfer and work done by the system.
The applied heat increases the internal energy of a system. Hence, conventionally heat is considered...