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Related Concept Videos

Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Types Of Superconductors01:28

Types Of Superconductors

A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
Superconductor01:24

Superconductor

A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Theory of Metallic Conduction01:17

Theory of Metallic Conduction

The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.

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Fabricating van der Waals Heterostructures with Precise Rotational Alignment
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Superconductivity in layered structure organometallic crystals.

F R Gamble, F J Disalvo, R A Klemm

    Science (New York, N.Y.)
    |May 1, 1970
    PubMed
    Summary

    Superconductivity is maintained in layered transition metal dichalcogenides even when organic molecules are inserted between layers. This research explores the relationship between organic molecules and superconductivity in these unique two-dimensional materials.

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    Area of Science:

    • Materials Science
    • Condensed Matter Physics
    • Solid-State Chemistry

    Background:

    • Layered transition metal dichalcogenides are known superconductors.
    • Intercalation of materials between layers can alter electronic properties.

    Purpose of the Study:

    • To investigate the effect of organic molecule intercalation on the superconductivity of layered transition metal dichalcogenides.
    • To explore the potential of these intercalated materials for studying organic molecule interactions with superconductivity.

    Main Methods:

    • Synthesis of intercalated transition metal dichalcogenide compounds.
    • Characterization of structural and superconducting properties.

    Main Results:

    • Superconductivity is preserved in layered transition metal dichalcogenides after intercalation with organic molecules.
    • The two-dimensional nature of these materials is maintained.

    Conclusions:

    • Organic molecule intercalation does not necessarily destroy superconductivity in these materials.
    • Intercalated transition metal dichalcogenides offer a platform for investigating the role of organic molecules in superconductivity.