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Gas Solubility01:31

Gas Solubility

Gas solubility in liquids forms liquid-gas solutions, such as soft drinks, where carbon dioxide is dissolved in water, and the ocean, where the solubility of oxygen and carbon dioxide supports marine life. The ability of oceans to dissolve gases impacts weather conditions in the troposphere.However, gas-liquid interactions vary. For instance, hydrogen chloride gas is highly soluble in water, while oxygen's solubility is much lower. Because these solutions are non-ideal, Raoult’s law, which...
Physical Properties Affecting Solubility02:19

Physical Properties Affecting Solubility

Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
Solubility03:00

Solubility

Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules, atoms, and/or ions)...
Physical Principles Governing Gas Exchange01:16

Physical Principles Governing Gas Exchange

Gas behavior plays a vital role in understanding bodily processes such as external and internal respiration. External respiration involves the diffusion of oxygen into the blood and carbon dioxide out of it in the lungs. In contrast, internal respiration happens in body tissues, where these gases move in opposite directions.
Gas Laws Governing Respiration
The behavior of gases is guided by Dalton's Law of partial pressures and Henry's Law.
Dalton's Law asserts that the total pressure exerted by...
Chemical and Solubility Equilibria02:21

Chemical and Solubility Equilibria

The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ΔGsolution is expressed as the balance of ΔGinteraction against the always-favorable free-energy of mixing, ΔGmixing. Solution formation is favorable if  ΔGsolution is less than zero, whereas it is unfavorable if ΔGsolution is greater than zero. In short, for a solution to form and complete dissolution to take place, the Gibbs energy change must be...

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Solubility of inert gases in PFC blood substitute, blood plasma, and mixtures.

Biomaterials, artificial cells, and immobilization biotechnology : official journal of the International Society for Artificial Cells and Immobilization Biotechnology·1992
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Related Experiment Video

Updated: Jul 12, 2026

Fizzy Extraction of Volatile Organic Compounds Combined with Atmospheric Pressure Chemical Ionization Quadrupole Mass Spectrometry
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Fizzy Extraction of Volatile Organic Compounds Combined with Atmospheric Pressure Chemical Ionization Quadrupole Mass Spectrometry

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Why gases dissolve in liquids.

G L Pollack

    Science (New York, N.Y.)
    |March 15, 1991
    PubMed
    Summary
    This summary is machine-generated.

    Predicting solubility from first principles remains challenging. This study presents xenon solubility experiments in organic solvents, bridging theory and experiment to identify gaps in current understanding.

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    Area of Science:

    • Thermodynamics
    • Statistical Mechanics
    • Physical Chemistry

    Background:

    • Thermodynamics and statistical mechanics provide a theoretical framework for solubility.
    • Quantitative prediction of solubility for real systems from first principles is difficult.

    Purpose of the Study:

    • Present results of solubility experiments in prototype solute-solvent systems.
    • Evaluate the extent to which these solubilities can be understood from molecular first principles.
    • Discuss limitations and missing elements in current predictive models.

    Main Methods:

    • Experimental determination of xenon solubility in simple organic solvents.
    • Comparison of experimental data with theoretical predictions derived from molecular first principles.

    Main Results:

    • Xenon solubility data presented for specific organic solvent systems.
    • Analysis of the agreement and discrepancies between experimental results and theoretical predictions.
    • Identification of areas where current first-principles approaches fall short.

    Conclusions:

    • Experimental solubility data provides a benchmark for theoretical models.
    • Understanding solubility from first principles requires further development.
    • Gaps in current theories highlight directions for future research in physical chemistry.