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The de Broglie Wavelength02:32

The de Broglie Wavelength

In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
Electron Behavior00:54

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Electrons are negatively charged subatomic particles that are attracted to an orbit around the positively-charged nucleus of an atom. They reside in locations that are associated with energy levels called shells and are further organized into sub-shells and orbitals within each shell.Electrons Orbit the NucleusElectrons are found in specific locations outside of the nucleus. The shell in which an electron resides indicates the general energy level of the electron: those closer to the nucleus...
Electron Behavior01:09

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Electrons are negatively charged subatomic particles attracted to and orbit around the positively-charged nucleus of an atom. They reside in spaces associated with energy levels called shells and are further organized into subshells and orbitals within each shell.
Electrons Orbit the Nucleus
Electrons are found in specific locations outside of the nucleus. The shell in which an electron resides indicates the general energy level of the electron: those closer to the nucleus have less energy,...
Resonance and Hybrid Structures02:16

Resonance and Hybrid Structures

According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Scanning Electron Microscopy01:07

Scanning Electron Microscopy

A scanning electron microscope (SEM) is used to study the surface features of a sample by using an electron beam that scans the sample surface in a two-dimensional manner. Typically, areas between ~1 centimeter to 5 micrometers in width can be imaged. SEM can be used to image bacteria, viruses, tissues as well as larger samples like insects. Conventional SEM gives a magnification ranging from 20X to 30,000X and spatial resolution of 50 to 100 nanometers.
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The Bohr Model02:18

The Bohr Model

Following the work of Ernest Rutherford and his colleagues in the early twentieth century, the picture of atoms consisting of tiny dense nuclei surrounded by lighter and even tinier electrons continually moving about the nucleus was well established. This picture was called the planetary model since it pictured the atom as a miniature “solar system” with the electrons orbiting the nucleus like planets orbiting the sun. The simplest atom is hydrogen, consisting of a single proton as the nucleus...

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Related Experiment Video

Updated: Jul 11, 2026

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
10:35

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals

Published on: May 29, 2018

The response of electrons to structural changes.

K B Wiberg, C M Hadad, C M Breneman

    Science (New York, N.Y.)
    |May 31, 1991
    PubMed
    Summary

    Molecular properties are dictated by electron distribution, analyzed via charge density from ab initio calculations. This method reveals substituent effects, structural changes, and electronic excitations, aiding chemical phenomenon analysis.

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    Area of Science:

    • Quantum Chemistry
    • Molecular Modeling

    Background:

    • Molecular properties are fundamentally determined by electron distribution.
    • Charge density, derived from wave functions, quantifies this electron distribution.

    Purpose of the Study:

    • To explore the utility of charge density analysis in understanding molecular properties.
    • To demonstrate how charge density reveals effects of molecular modifications and electronic states.

    Main Methods:

    • Utilizing ab initio molecular orbital calculations to obtain wave functions.
    • Analyzing charge density through methods like projection density or charge difference plots.
    • Partitioning charge density to calculate atomic properties via numerical integration.

    Main Results:

    • Charge density analysis provides insights into substituent effects and structural changes.
    • Electronic excitation impacts on molecular properties can be elucidated.
    • Atomic properties such as charges and dipoles can be quantified.

    Conclusions:

    • Charge density is a versatile tool for analyzing molecular properties and chemical phenomena.
    • Ab initio calculations coupled with charge density analysis offer a powerful approach in computational chemistry.