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New xenicanes from Xenia viridis
Jaime Raul O Janairo1, Gerardo C Janairo, Consolacion Y Ragasa
1Chemistry Department and Center for Natural Sciences and Ecological Research, De La Salle University 2401, Taft Avenue, Manila, Philippines.
Abstract:
The dichloromethane extract of Xenia viridis afforded two new xenicane diterpenoids (3 and 4) by silica gel chromatography. The oxirane ring of 3 was found to be susceptible to a slow ring opening under acidic conditions to afford 5. Their structures were elucidated by extensive 1D and 2D NMR spectroscopy.
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