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Characterization of Synthetic Polymers via Matrix Assisted Laser Desorption Ionization Time of Flight (MALDI-TOF) Mass Spectrometry
Published on: June 10, 2018
Amylose selectively includes one from a mixture of two resemblant polyethers in vine-twining polymerization
Yoshiro Kaneko1, Koutarou Beppu, Jun-Ichi Kadokawa
1Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, Kagoshima, Japan.
Abstract:
In this paper, we describe that amylose almost selectively includes poly(tetrahydrofuran) (PTHF) from a mixture of poly(oxetane) (POXT) and PTHF having resemblant chemical structures and molecular weights in vine-twining polymerization. This was performed by the phosphorylase-catalyzed enzymatic polymerization of alpha-D-glucose 1-phosphate from maltoheptaose as a primer in the presence of a mixture of POXT and PTHF to produce an amylose-PTHF inclusion complex.
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