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Updated: Jan 20, 2026
Lewis Acid-Base Interaction in Ph3P-BH3
Published on: April 29, 2023
AuCl-catalyzed synthesis of benzyl-protected substituted phenols: a formal [3+3] approach
1Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA.
Abstract:
A AuCl-catalyzed synthesis of highly substituted, benzyl-protected phenols is developed. This reaction unites enal/enones and benzyl allenyl ether in a [3+3] fashion in two steps, allowing flexibility in phenol synthesis and excellent control of substitution at the benzene ring.
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Lewis Acid-Base Interaction in Ph3P-BH3
One of the goals of chemistry is to use models that account for trends and provide insights into the properties of reactants that contribute to reactivity. Substances have been classified as acids and bases since the time of the ancient Greeks, but the definition of acids and bases has been modified and expanded over the years.1
The ancient Greeks would characterize substances by taste, and defined acids as those...
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Formal Charges