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Stable copper-nitrosyl formation by nitrite reductase in either oxidation state

Elitza I Tocheva1, Federico I Rosell, A Grant Mauk

  • 1Department of Microbiology and Immunology, Life Sciences Institute, University of British Columbia, 2350 Health Sciences Mall, Vancouver BC, V6T 1Z3, Canada.

Biochemistry
|October 11, 2007
PubMed
Summary

Researchers characterized copper-nitrosyl intermediates in nitrite reductase (NiR) using X-ray crystallography. They identified a stable Cu(II)-NO- species, offering new insights into bacterial denitrification mechanisms.

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