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Updated: Jul 11, 2026

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Published on: March 6, 2017
Semiclassical wave packet treatment of scattering resonances: application to the delta zero-point energy effect in
Evgeny Vetoshkin1, Dmitri Babikov
1Chemistry Department, Marquette University, Milwaukee, Wisconsin 53201, USA.
Abstract:
For the first time Feshbach-type resonances important in recombination reactions are characterized using the semiclassical wave packet method. This approximation allows us to determine the energies, lifetimes, and wave functions of the resonances and also to observe a very interesting correlation between them. Most important is that this approach permits description of a quantum delta-zero-point energy effect in recombination reactions and reproduces the anomalous rates of ozone formation.
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