Source apportionment of PM(10) and PM(2.5) using positive matrix factorization and chemical mass balance in Izmir,

Sinan Yatkin1, Abdurrahman Bayram

  • 1Dokuz Eylul University, Faculty of Engineering, Department of Environmental Engineering, Kaynaklar Campus, 35160 Buca, Izmir, Turkey. sinan.yatkin@deu.edu.tr

Insights

Traffic emissions were the dominant source of particulate matter (PM) pollution in Izmir, Turkey, accounting for over 70% of air concentrations. Other minor contributors included fossil fuel burning and industrial activities.

Area of Science:

  • Environmental Science
  • Atmospheric Chemistry
  • Air Quality Monitoring

Background:

  • Atmospheric particulate matter (PM) poses significant environmental and health risks.
  • Understanding PM sources is crucial for effective air quality management.
  • Izmir, Turkey, experiences varying levels of air pollution due to its urban and suburban settings.

Purpose of the Study:

  • To identify and quantify the sources contributing to PM10 and PM2.5 concentrations in Izmir.
  • To compare the effectiveness of different source apportionment models.

Main Methods:

  • Concurrent sampling of PM10 and PM2.5 from June 2004 to May 2005 at urban and suburban sites.
  • Elemental composition analysis using inductively coupled plasma-optical emission spectrometry.
  • Application of Positive Matrix Factorization (PMF) and Chemical Mass Balance (CMB) modeling.

Main Results:

  • PMF identified fossil fuel burning, traffic, mineral industries, and marine salt as major contributors, but with over 40% undetermined sources.
  • CMB modeling successfully apportioned all PM contributions, identifying traffic as the dominant source (>70%) at both sites.
  • Minor contributors identified by CMB included fossil fuel burning, mineral industries, marine salt, and a natural gas-fired power plant.

Conclusions:

  • Traffic emissions are the primary source of particulate matter pollution in Izmir.
  • CMB modeling provided a more complete source apportionment compared to PMF in this study.
  • Effective air quality strategies in Izmir should prioritize traffic emission control.

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