Related Experiment Video
Updated: Jul 10, 2026
Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
Published on: March 24, 2019
Magnetic properties and magnetic structures of Cu3(OD)4XO4, X=Se or S: cycloidal versus collinear antiferromagnetic
Serge Vilminot1, Gilles André, Francoise Bourée-Vigneron
1Groupe des Matériaux Inorganiques, IPCMS, UMR 7504 CNRS-ULP, 23 rue du Loess, BP 43, 67034 Strasbourg Cedex 2, France. vilminot@ipcms.u-strasbg.fr
Abstract:
We report a comparative study of the magnetic properties of synthetic Cu3(OH)4(SO4)x(SeO4)1-x and the magnetic structures of the parent compounds. All compounds are isostructural and belong to the orthorhombic class of parent compounds. They consist of 3-legged ribbons of edge-sharing copper octahedra connected by micro3-OH and XO4 (X=S or Se). XO4 acts both as one-atom and three-atom bridges to connect seven Cu atoms (six Cu(2) and one Cu(1)) belonging to three neighboring ribbons. The two end members behave as low-dimensional AF with a long-range antiferromagnetic state below 5 (X=S) and 8 K (X=Se); the former shows evidence of a canting. Analyses of the neutron powder diffraction data for X=S were shown to display an ordered magnetic state (k=0 0 0) where the moments of Cu(2) within the two outer legs are collinear and parallel within each leg but antiparallel from each other; the orientation of the moments of Cu(2) is the c axis. In contrast, for X=Se k=approximately 1/7 0 0 and the magnetic structure is cycloidal and transforms progressively from being incommensurate (T>3 K) to commensurate (T
More Related Videos
08:55Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
06:53Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Related Concept Videos
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
02:42Valence Bond Theory
02:42Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
02:37Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
01:31Ferromagnetism