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Neocrocin A: a novel crocetin glycoside with a unique system for binding sugars isolated from gardenia yellow
Yoshinori Uekusa1, Naoki Sugimoto, Kyoko Sato
1School of Life Science, Tokyo University of Pharmacy and Life Science, Hachioji, Tokyo, Japan.
Abstract:
A novel crocetin glycosyl ester, neocrocin A (2), was isolated from gardenia yellow. The structure of 2 was elucidated as that of an all-trans-crocetin beta-D-gentiobiosyl beta-D-glucopyranosyl-(1-->6)-D-2-deoxy-glucopyranos-2-yl diester based on chemical and spectral data. The findings provide evidence that the binding system of crocetin glycosides is not limited to the anomeric position.
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