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Effect of shear on an onion texture
1MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, New Zealand.
Shear stress transforms surfactant lamellar systems into spherical onions. Nuclear magnetic resonance (NMR) reveals how onion size and local viscosity change with shear rate, impacting solvent diffusion and slip.
Area of Science:
- Soft Matter Physics
- Materials Science
- Physical Chemistry
Background:
- Lamellar systems are surfactant self-assemblies forming planar bilayers.
- High shear rates induce the formation of spherical multi-lamellar vesicles, known as onions.
- Understanding shear effects on these structures is crucial for materials processing and applications.
Purpose of the Study:
- To investigate the impact of shear rate on multi-lamellar vesicles (onions).
- To characterize solvent diffusion and onion structure under varying shear conditions.
- To determine the relationship between local viscosity, onion size, and shear stress.
Main Methods:
- Utilized nuclear magnetic resonance (NMR) to measure solvent diffusion via time-dependent mean-squared displacements.
- Employed NMR velocimetry to analyze onion structure and dynamics.
- Investigated the role of slip and determined stress-dependent wall slip velocities.
Main Results:
- Identified distinct regimes of onion structure formation as a function of shear rate.
- Established a correlation between local viscosity and onion size across different shear regimes.
- Quantified the stress dependence of wall slip velocities in the sheared lamellar systems.
Conclusions:
- Shear rate significantly influences the structure and dynamics of surfactant onions.
- NMR techniques provide powerful insights into the relationship between macroscopic shear and microscopic structure.
- The findings contribute to understanding the rheology and self-assembly of complex fluids under flow.
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