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Research and Development of High-performance Explosives
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Method development study for APR cartridge evaluation in fire overhaul exposures.

T Renée Anthony1, Philip Joggerst, Leonard James

  • 1Mel and Enid Zuckerman College of Public Health, University of Arizona, 1295 North Martin Avenue, Tucson, AZ 85723-5210, USA. tra@email.arizona.edu

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Firefighter respirator cartridges show limited effectiveness against smoke during overhaul. While some irritants are filtered, formaldehyde and acetaldehyde can still pose risks, especially under stricter exposure limits.

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Area of Science:

  • Occupational Health and Safety
  • Environmental Science
  • Chemical Engineering

Background:

  • Firefighters often forgo respiratory protection during overhaul, despite proposed solutions like multi-gas cartridges.
  • Residential fire smoke contains numerous hazardous contaminants, posing significant inhalation risks.

Purpose of the Study:

  • To develop and validate a method for assessing respirator cartridge effectiveness against residential fire overhaul smoke.
  • To quantify firefighter exposure to specific contaminants during overhaul activities.

Main Methods:

  • Chamber tests were conducted to measure 91 contaminants and particulates in smoke.
  • Respirator cartridge penetration was analyzed for various chemical and particulate agents.
  • An exposure index was calculated to assess aggregate respiratory irritant risk.

Main Results:

  • Respirator cartridges detected some penetrating compounds, though styrene, benzene, acrolein, and particulates were not found in limited tests.
  • Formaldehyde and acetaldehyde were primary contributors to the irritant index in filtered air.
  • Cartridge effectiveness varied, failing to meet the National Institute for Occupational Safety and Health Recommended Exposure Limit (NIOSH REL) for formaldehyde in some cases.

Conclusions:

  • Current respirator cartridges may not adequately protect firefighters from aggregate respiratory irritants in overhaul smoke, particularly concerning formaldehyde.
  • The developed testing method provides a framework for future evaluations, recommending specific contaminants and additional irritant gases.
  • Further research is needed to fully assess the efficacy of air-purifying respirators against the complex mixture of overhaul smoke constituents.