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Updated: Jul 10, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Tetrakis(1-naphthylamino)silane and its tetrahydrofuran trisolvate
Maravanji S Balakrishna1, Tristram Chivers, Masood Parvez
1Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India.
Abstract:
In both title structures, C(40)H(32)N(4)Si and C(40)H(32)N(4)Si.3C(4)H(8)O, the angles around the Si atom deviate significantly from the tetrahedral value [104.34 (7)-116.63 (7) degrees in the nonsolvate and 99.91 (15)-116.85 (15) degrees in the solvate]. The amino H atoms in the solvated structure are involved in hydrogen bonding with two of the tetrahydrofuran solvent molecules.
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