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Related Concept Videos

¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Electromagnetic Wave Equation01:24

Electromagnetic Wave Equation

Maxwell's equations for electromagnetic fields are related to source charges, either static or moving. These fields act on a test charge, whose trajectory can thus be determined using suitable boundary conditions. The objective of electromagnetism is thus theoretically complete.
However, although electric and magnetic fields were first introduced as mathematical constructs to simplify the description of mutual forces between charges, a natural question emerges from Maxwell's equations: What...
Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the involved orbitals. The...
Euler Equations of Motion01:19

Euler Equations of Motion

Imagine a rigid body that is rotating at an angular velocity of ω within an inertial frame of reference. Along with this, picture a second rotating frame that is attached to the body itself. This frame moves along with the body and possesses an angular velocity of Ω. The total moment about the center of mass is calculated by adding the rate of change of angular momentum about the center of mass in relation to the rotating frame and the cross-product of the body's angular velocity and its...
Equations of Wave Motion01:02

Equations of Wave Motion

Mathematically, the motion of a wave can be studied using a wavefunction. Consider a string oscillating up and down in simple harmonic motion, having a period T. The wave on the string is sinusoidal and is translated in the positive x-direction as time progresses. Sine is a function of the angle θ, oscillating between +A and −A and repeating every 2π radians. To construct a wave model, the ratio of the angle θ and the position x is considered.

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Related Experiment Video

Updated: Jul 10, 2026

Magnetically Induced Rotating Rayleigh-Taylor Instability
06:42

Magnetically Induced Rotating Rayleigh-Taylor Instability

Published on: March 3, 2017

Generalized rotating-wave approximation for arbitrarily large coupling.

E K Irish1

  • 1School of Mathematics and Physics, Queen's University Belfast, Belfast BT7 1NN, United Kingdom. e.irish@qub.ac.uk

Physical Review Letters
|November 13, 2007
PubMed
Summary

A new generalized rotating-wave approximation improves energy level accuracy for spin-boson Hamiltonians. This enhanced method is accurate across various coupling strengths and detunings, benefiting solid-state experiments.

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Last Updated: Jul 10, 2026

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Area of Science:

  • Quantum mechanics
  • Condensed matter physics

Background:

  • The spin-boson Hamiltonian is a fundamental model in quantum mechanics describing the interaction between a two-level system and a bosonic bath.
  • The rotating-wave approximation (RWA) is a common technique used to simplify calculations involving such systems, but it has limitations.

Purpose of the Study:

  • To present a generalized version of the rotating-wave approximation for the single-mode spin-boson Hamiltonian.
  • To demonstrate that this generalized approximation yields more accurate energy level expressions compared to standard methods.

Main Methods:

  • A generalized rotating-wave approximation was developed.
  • A specific change of basis was performed before eliminating off-resonant terms in the Hamiltonian.

Main Results:

  • The generalized approximation provides a significantly more accurate expression for the system's energy levels.
  • The method's accuracy is maintained for all coupling strengths.
  • It is also effective for a wide range of detuning values.

Conclusions:

  • The generalized rotating-wave approximation offers improved accuracy for the spin-boson model.
  • This method is applicable across diverse parameter regimes.
  • Potential applications exist in experimental solid-state physics.