Related Experiment Video
Updated: Jul 10, 2026

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Bose-Einstein condensation in semiconductors: the key role of dark excitons
Monique Combescot1, Odile Betbeder-Matibet, Roland Combescot
1Institut des NanoSciences de Paris, Université Pierre et Marie Curie, CNRS, Campus Boucicaut, 140 rue de Lourmel, 75015 Paris, France.
Abstract:
Bose-Einstein condensation in semiconductors is controlled by the nonelementary-boson nature of excitons. Pauli exclusion between the fermionic components of composite excitons produces dramatic exchange couplings between bright and dark states. In microcavities, where bright excitons and photons form polaritons, they force the condensate to be linearly polarized, as observed. In bulk, they also force linear polarization, but of dark states, due to interband Coulomb scatterings. To evidence this dark condensate, indirect processes are thus needed.
Related Concept Videos
Semiconductors
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Fermi Level Dynamics
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
Types of Semiconductors
Fermi Level
At absolute zero temperature, electrons fill all energy states up to the Fermi level, leaving upper states empty. As the temperature rises,...
Energy Bands in Solids
Band Formation:
When atoms are brought close together, as in a solid, these discrete energy levels begin to split due to the overlap of electron orbitals from adjacent atoms. This split occurs because of the Pauli exclusion principle, which states that no two...
Carrier Generation and Recombination
This process is given by the generation rate G and is efficient due to the conservation of momentum between the valence band maximum and conduction band minimum.
Indirect generation involves an...

