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Structure and synthesis of nectrisine, a new immunomodulator isolated from a fungus
H Kayakiri1, K Nakamura, S Takase
1Exploratory Research Laboratories, Fujisawa Pharmaceutical Co., Ltd., Ibaraki, Japan.
Chemical & Pharmaceutical Bulletin
|November 1, 1991
Abstract:
The structure of a novel immunomodulator, nectrisine (1), has been elucidated on the basis of chemical and spectroscopic evidence. Its absolute stereochemistry was predicted on the basis of the dibenzoate chirality rule and finally confirmed by a synthesis from D-glucose.