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Synthesis of two repeat units corresponding to the backbone of the pectic polysaccharide rhamnogalacturonan I
Dominic Reiffarth1, Kerry B Reimer
1Department of Chemistry, University of Northern British Columbia, 3333 University Way, Prince George, British Columbia, Canada V2N 4Z9.
Abstract:
A tetrasaccharide corresponding to a sequence of the rhamnogalacturonan I backbone has been synthesized. This synthesis relies on only two protected monosaccharides and proceeds through a common disaccharide intermediate. Synthesis of this tetrasaccharide has been designed to allow for the addition of branching elements at the 4-positions of the rhamnosyl units, or further chain elongation at the 2-position.
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