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A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes on artificial peptides in
Kentaro Tanaka1, Kenji Kaneko, Yusuke Watanabe
1Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.
Dalton Transactions (Cambridge, England : 2003)
|November 21, 2007
Abstract:
A template-directed synthetic approach to halogen-bridged mixed-valence platinum complexes has been performed in organic media using, for instance, a synthetic peptide bearing two bis(ethylenediamine)-based Pt(IV) complexes with two axial bromide anionic ligands, [(Pt(IV)Br2(en))2](RSO3)4, and a [Pt(II)(en)2](RSO3)2 complex (R = (C12H25OCH2)2CHO(CH2)3-).
