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Related Concept Videos

Potential Due to a Polarized Object01:29

Potential Due to a Polarized Object

A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
Group Polarization01:01

Group Polarization

Group polarization is the strengthening of an original group attitude following the discussion of views within a group (Teger & Pruitt, 1967). That is, if a group initially favors a viewpoint, after discussion the group consensus is likely a stronger endorsement of the viewpoint. Conversely, if the group was initially opposed to a viewpoint, group discussion would likely lead to stronger opposition.
Thermal Sigmatropic Reactions: Overview01:16

Thermal Sigmatropic Reactions: Overview

Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...
Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
Thermal Electrocyclic Reactions: Stereochemistry01:17

Thermal Electrocyclic Reactions: Stereochemistry

The stereochemistry of electrocyclic reactions is strongly influenced by the orbital symmetry of the polyene HOMO. Under thermal conditions, the reaction proceeds via the ground-state HOMO.
Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.

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A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
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Published on: September 5, 2019

Polarization rotation induced by cascaded third-order processes.

N Minkovski, S M Saltiel, G I Petrov

    Optics Letters
    |November 23, 2007
    PubMed
    Summary

    Researchers observed intensity-dependent polarization rotation in YVO(4) crystals, linked to nonlinear optical processes. This effect, proportional to input intensity and crystal length, provides new insights into cubic susceptibility.

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    Area of Science:

    • Nonlinear Optics
    • Solid-State Physics
    • Crystallography

    Background:

    • Cubic susceptibility describes a material's nonlinear optical response.
    • Self-phase modulation and four-wave mixing are key third-order nonlinear optical processes.

    Purpose of the Study:

    • To experimentally observe and characterize intensity-dependent polarization rotation.
    • To investigate the relationship between this rotation and the real part of cubic susceptibility.

    Main Methods:

    • Utilizing a YVO(4) crystal.
    • Observing polarization rotation along the crystal's fourfold axis.
    • Analyzing the dependence on input intensity and crystal length.

    Main Results:

    • Demonstrated intensity-dependent polarization rotation.
    • Found the rotation angle is proportional to the square of the input intensity-crystal length product.
    • Established a link between this rotation and the real part of cubic susceptibility.

    Conclusions:

    • This study provides the first experimental evidence connecting intensity-dependent polarization rotation to the real part of cubic susceptibility.
    • The findings enhance understanding of nonlinear optical phenomena in crystals.
    • YVO(4) crystals exhibit significant nonlinear optical properties.