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Updated: Jul 9, 2026

Self-Nanoemulsification of Healthy Oils to Enhance the Solubility of Lipophilic Drugs
Published on: July 27, 2022
Effect of ionic surfactants on drainage and equilibrium thickness of emulsion films
Stoyan I Karakashev1, Emil D Manev, Roumen Tsekov
1Division of Chemical Engineering, School of Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia.
Abstract:
This paper presents new theoretical and experimental results that quantify the role of surfactant adsorption and the related interfacial tension changes and interfacial forces in the emulsion film drainage and equilibrium. The experimental results were obtained with plane-parallel microscopic films from aqueous sodium dodecyl sulphate solutions formed between two toluene droplets using an improved micro-interferometric technique. The comparison between the theory and the experimental data show that the emulsion film drainage and equilibrium are controlled by the DLVO interfacial forces. The effect of interfacial viscosity and interfacial tension gradient (the Marangoni number) on the film drainage is also significant.
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