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Formation of trisaccharides (kestoses) by pyrolysis of sucrose
M Manley-Harris1, G N Richards
1Wood Chemistry Laboratory, University of Montana, Missoula 59812.
Abstract:
Amorphous sucrose, containing citric acid as catalyst, undergoes thermolysis at 100 degrees to yield fructofuranosyl cation and D-glucose. The cation reacts with unchanged sucrose to form all three of the known kestoses, and also their alpha-fructofuranosyl anomers. Two of the latter are resistant to invertase hydrolysis. A new fructosylglucose disaccharide is also formed.
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