Extending the scope of singlet-state spectroscopy.

Riddhiman Sarkar1, Puneet Ahuja, Detlef Moskau

  • 1Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Batochime, 1015 Lausanne, Switzerland.

Summary

New radio-frequency (RF) pulse sequences, including sinc and RE-BURP, significantly extend the lifetime of singlet states in nuclear magnetic resonance (NMR). These advanced decoupling methods improve measurements of spin systems with large chemical shift differences, like those in uracil and proteins.

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