Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Double Resonance Techniques: Overview01:12

Double Resonance Techniques: Overview

Double resonance techniques in Nuclear Magnetic Resonance (NMR) spectroscopy involve the simultaneous application of two different frequencies or radiofrequency pulses to manipulate and observe two distinct nuclear spins. One important application of double resonance is spin decoupling, which selectively suppresses coupling with one type of nucleus while observing the NMR signal from another nucleus, simplifying the spectrum and enhancing resolution.
Spin decoupling is usually achieved by...
Nuclear Overhauser Enhancement (NOE)01:06

Nuclear Overhauser Enhancement (NOE)

Irradiation of a spin-active nucleus causes an increase or decrease in the signal intensity of neighboring nuclei that are not necessarily chemically bonded or involved in J-coupling. This phenomenon, called the nuclear Overhauser enhancement (NOE), results from through-space interactions between the nuclear spins. The NOE effect decreases with increasing internuclear distance and is generally not observed beyond 4 angstroms. In NOE, dipole-dipole interactions between neighboring spin-active...
Resonance and Hybrid Structures02:16

Resonance and Hybrid Structures

According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Atomic Nuclei: Magnetic Resonance01:05

Atomic Nuclei: Magnetic Resonance

The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
¹H NMR: Interpreting Distorted and Overlapping Signals01:02

¹H NMR: Interpreting Distorted and Overlapping Signals

Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Different antigenic nature in apparently healthy women with high serum CA 125 levels compared with typical patients with ovarian cancer.

Cancer·1992
Same author

Paraneoplastic cerebellar degeneration: successful early detection and treatment of cancer through characterization of the anti-Purkinje cell antibody.

Internal medicine (Tokyo, Japan)·1992
Same author

Comparison of specific reactivity of monoclonal and polyclonal ABH reactive antibodies.

Nihon hoigaku zasshi = The Japanese journal of legal medicine·1992
Same author

A novel method for blood group typing with the aid of monoclonal antibody immobilized dyed microspheres.

Nihon hoigaku zasshi = The Japanese journal of legal medicine·1992
Same author

Detection of human papillomavirus DNA in invasive cervical cancers by the polymerase chain reaction and its clinical significance.

Acta pathologica japonica·1992
Same author

Hepatocellular carcinoma containing endocrine cells. An autopsy report of triplecancer involving the liver, kidney and thyroid.

Acta pathologica japonica·1992

Related Experiment Video

Updated: Jul 9, 2026

Simultaneous Label-Free Autofluorescence Multi-Harmonic Microscopy
09:19

Simultaneous Label-Free Autofluorescence Multi-Harmonic Microscopy

Published on: August 29, 2025

Enhanced nonlinearity and transparency via autoionizing resonance.

T Nakajima

    Optics Letters
    |December 8, 2007
    PubMed
    Summary
    This summary is machine-generated.

    Researchers analyzed the nonlinear response of autoionizing media. They found that tuning two radiation fields can enhance nonlinearities while canceling absorption, especially in the VUV region.

    More Related Videos

    High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy
    10:40

    High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy

    Published on: June 28, 2016

    Direct Imaging of Laser-driven Ultrafast Molecular Rotation
    10:52

    Direct Imaging of Laser-driven Ultrafast Molecular Rotation

    Published on: February 4, 2017

    Related Experiment Videos

    Last Updated: Jul 9, 2026

    Simultaneous Label-Free Autofluorescence Multi-Harmonic Microscopy
    09:19

    Simultaneous Label-Free Autofluorescence Multi-Harmonic Microscopy

    Published on: August 29, 2025

    High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy
    10:40

    High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy

    Published on: June 28, 2016

    Direct Imaging of Laser-driven Ultrafast Molecular Rotation
    10:52

    Direct Imaging of Laser-driven Ultrafast Molecular Rotation

    Published on: February 4, 2017

    Area of Science:

    • Atomic and Molecular Physics
    • Quantum Optics
    • Nonlinear Optics

    Background:

    • Autoionizing media exhibit complex responses to electromagnetic fields.
    • Nonradiative interactions play a crucial role in establishing coherence within these media.
    • Understanding and controlling nonlinear optical properties is essential for advanced applications.

    Purpose of the Study:

    • To analyze the nonlinear response of an autoionizing medium.
    • To investigate methods for enhancing third-order nonlinearities.
    • To explore the cancellation of absorption in such systems.

    Main Methods:

    • Theoretical analysis of the nonlinear response.
    • Modeling coherence established by nonradiative interactions.
    • Investigating the effect of tuning two radiation fields.

    Main Results:

    • Coherence in autoionizing media can be established via nonradiative interactions.
    • Third-order nonlinearities can be significantly enhanced.
    • Absorption can be simultaneously canceled by proper tuning of radiation fields.
    • The proposed scheme shows particular utility in the vacuum ultraviolet (VUV) region.

    Conclusions:

    • A method for enhancing nonlinearities in autoionizing media has been identified.
    • The cancellation of absorption alongside nonlinearity enhancement is demonstrated.
    • This technique offers a promising pathway for nonlinear optics applications, especially in the VUV spectrum.